答                                                  元の問題へ  


問i の答      510 [mol]


 H2SO4 の分子量が 1.0×2 + 32.0×1 + 16.0×4 = 98 であるので, モル質量 M(H2SO4) [g mol-1] は分子量の値に等しく, すなわち,

                        M(H2SO4) = 98 [g mol-1]

 そこで, 50 kg の硫酸の物質量 n(H2SO4) [mol] は,

                   n(H2SO4) = (50×103)/98 = 510 [mol] (有効数字3桁)


Answer of Qi 
    510 [mol]


 As the molecular weight of H2SO4 is 1.0×2 + 32.0×1 + 16.0×4 = 98, the molar mass, M(H2SO4) [g mol-1], is equal to the value of the molecular weight, i.e.,

                          M(H2SO4) = 98 [g mol-1],

 so the amount in moles of 50 kg of sulphuric acid, n(H2SO4) [mol] is

                   n(H2SO4) = (50×103)/98 = 510 [mol] (3 sig. figs)


問ii の答       1.02 [k mol]


 水酸化ナトリウムが硫酸と次のように反応することを考慮する :

                 2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l)

 上の反応に対して, NaOH : H2SO4 のモル比は 2 : 1 であるので, NaOH の物質量 n(NaOH) は, 問iiでの硫酸の 510 [mol] を用いて, 次のように計算される。

              n(NaOH) = 510×2 = 1020 [mol] = 1.02 [k mol] (有効数字3桁)


Answer of Qii      1.02 [k mol]


 Consider that sodium hydroxide reacts with sulphuric acid as follows :

                 2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l)

 For the reaction above, as the mole ratio of NaOH : H2SO4 is 2 : 1, the amount in moles of NaOH, n(NaOH), is calculated as follows, using 510 [mol] of the sulphuric acid in Qi.

               n(NaOH) = 510×2 = 1020 [mol] = 1.02 [k mol] (3 sig. fig.)


問iii の答       204 [dm3]


 NaOH の物質量 1.02 [k mol] を用いて, このモル数 1.02 [k mol] を含む 5 M NaOH (ここで M は M mol dm-3) の体積 X [dm3] を計算する。

 そこで次の式が成立する :

                            5X = 1.02×103,

 よって,

                            X = 204 [dm3].


Answer of Qiii       204 [dm3]


 Use the amount in moles of NaOH, 1.02 [k mol], to calculate the volume of 5 M (where M mol dm-3) NaOH, X [dm3], which contains this number of moles, 1.02 [k mol].

 And so we have the following equation :

                            5X = 1.02×103,

 accordingly,

                            X = 204 [dm3].