答 元の問題へ
問i の答 510 [mol]
H2SO4 の分子量が 1.0×2 + 32.0×1 + 16.0×4 = 98 であるので, モル質量 M(H2SO4) [g mol-1] は分子量の値に等しく, すなわち,
M(H2SO4) = 98 [g mol-1]
そこで, 50 kg の硫酸の物質量 n(H2SO4) [mol] は,
n(H2SO4) = (50×103)/98 = 510 [mol] (有効数字3桁)
Answer of Qi 510 [mol]
As the molecular weight of H2SO4 is 1.0×2 + 32.0×1 + 16.0×4 = 98, the molar mass, M(H2SO4) [g mol-1], is equal to the value of the molecular weight, i.e.,
M(H2SO4) = 98 [g mol-1],
so the amount in moles of 50 kg of sulphuric acid, n(H2SO4) [mol] is
n(H2SO4) = (50×103)/98 = 510 [mol] (3 sig. figs)
問ii の答 1.02 [k mol]
水酸化ナトリウムが硫酸と次のように反応することを考慮する :
2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l)
上の反応に対して, NaOH : H2SO4 のモル比は 2 : 1 であるので, NaOH の物質量 n(NaOH) は, 問iiでの硫酸の 510 [mol] を用いて, 次のように計算される。
n(NaOH) = 510×2 = 1020 [mol] = 1.02 [k mol] (有効数字3桁)
Answer of Qii 1.02 [k mol]
Consider that sodium hydroxide reacts with sulphuric acid as follows :
2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l)
For the reaction above, as the mole ratio of NaOH : H2SO4 is 2 : 1, the amount in moles of NaOH, n(NaOH), is calculated as follows,
using 510 [mol] of the sulphuric acid in Qi.
n(NaOH) = 510×2 = 1020 [mol] = 1.02 [k mol] (3 sig. fig.)
問iii の答 204 [dm3]
NaOH の物質量 1.02 [k mol] を用いて, このモル数 1.02 [k mol] を含む 5 M NaOH (ここで M は
M mol dm-3) の体積 X [dm3] を計算する。
そこで次の式が成立する :
5X = 1.02×103,
よって,
X = 204 [dm3].
Answer of Qiii 204 [dm3]
Use the amount in moles of NaOH, 1.02 [k mol], to calculate the volume
of 5 M (where M mol dm-3) NaOH, X [dm3], which contains this number of moles, 1.02 [k mol].
And so we have the following equation :
5X = 1.02×103,
accordingly,
X = 204 [dm3].